RESEARCH INTO KINETIC REGULARITIES OF CATALYTIC LIQUID-PHASE OXIDATION OF n-HEXADECANE IN THE PRESENCE OF METALCOMPLEXES CALALYSTS

Abstract

Kinetic regularities of catalytic liquid-phase oxidation of n-hexadecane in the presence of metal complexes of variable valence were studied. In the reaction of n-hexadecane oxidation as a catalytic mixture, a complex o-phenanthroline with stearate with variable valence metals (Mn2+, Cu2+, Co2+) was used. It found that o-phenanthroline significantly influences the catalytic activity of metal ions. The introduction of organic ligand into the catalytic system, as well as varying the ligand: metal salt ratio, has effect greatly on the course and character of the process.

Catalytic Oxidation of Oxygen Containing Aliphatic Hydrocarbons in the Presence of Metalpolymer Complexes

“…Proceeding from the analysis [10][11][12] of the regularities of liquid-phase oxidation of saturated hydrocarbons, it revealed that the primary products of the starting stage of oxidation are hydroperoxides, and their decomposition mostly leads to the formation of carbonyl complexes and alcohols. However, it should be emphasized that the latter ones, being in reaction zone under the influence of oxygen, are subjected to further oxidation to form carbonic acids, complicated ethers, carbon dioxide and the products of condensation.…”