Tautosyllabic segment sequences exhibit greater gestural overlap than heterosyllabic ones. In Spanish, it is presumed that word-final consonants followed by a word-initial vowel undergo resyllabification, and generative phonology assumes that canonical CV.CV# and derived CV.C#V onsets are structurally identical. However, recent studies have not found evidence of this structural similarity in the acoustics. The current goal is to investigate anticipatory and carryover vowel nasalization patterns in tautosyllabic, heterosyllabic, and resyllabified segment sequences in Spanish. Nine native speakers of Peninsular Spanish participated in a read-aloud task. Nasal airflow data were extracted using pressure transducers connected to a vented mask. Each participant produced forty target tokens with CV.CV# (control), CVN# (tautosyllabic), CV.NV# (heterosyllabic), and CV.N#V (resyllabification) structures. Forty timepoints were obtained from each vowel to observe airflow dynamics, resulting in a total of 25,200 datapoints analyzed. Regarding anticipatory vowel nasalization, the CVN# sequence shows an earlier onset of nasalization, while CV.NV# and CV.N#V sequences illustrate parallel patterns among them. Carryover vowel nasalization exhibited greater nasal spreading than anticipatory nasalization, and vowels in CV.NV# and CV.N#V structures showed symmetrical nasalization patterns. These results imply that syllable structure affects nasal gestural overlap and that aerodynamic characteristics of vowels are unaffected across word boundaries.