Spin-polarized atoms have applications in many areas such as biological magnetic resonance imaging, optical magnetometry, atomic clocks and fundamental symmetry studies. Polarized atoms are often held in a container, most commonly a glass cell. Their interactions with the walls of the container during their collisions with the walls are often the main cause of spin relaxation, which determines the ultimate attainable polarization, and frequency shift, which for example affects the long term frequency stability in atomic clocks. This paper presents a critical review of the studies done in the past six decades of the wall interactions of spin-polarized atoms, including the hydrogen atom, alkali metal atoms, and diamagnetic atoms with 1 S0 ground states such as mercury, cadmium and noble gas atoms. It summarizes the progress that has been made in understanding the nature of wall interactions and the physical mechanisms of spin relaxation and frequency shift due to wall collisions. It also points out those issues, particularly in connection with the widely used anti-relaxation coatings, that remain to be understood.
CONTENTSI. Introduction 1 II. Wall Interactions of Spin-Polarized Diamagnetic Atoms with 1 S 0 Ground States and Nuclear Spins I ≥ 1 2 A. The nature of the wall interactions 2 B. Quadrupole wall interaction − theory 3 1. Boundary condition 3 2. Perturbation theory 4 C. Quadrupole wall interaction − experiment 5 III. Wall Interactions of Spin-Polarized Noble Gas Atoms with Nuclear Spins I = 1/2 8 A. The nature of the wall interactions 8 B. Wall relaxation of 3 He 9 C. Wall relaxation of 129 Xe 11 1. Mechanisms 11 2. Theory 12 3. Experiments 13 D. Cross polarization 13