Research on Binary Phase Equilibrium for 1-Methylnaphthalene + CO₂

Abstract

High-pressure vapor−liquid equilibrium data for the binary system of 1-methylnaphthalene + CO 2 were measured using a set of visible phase equilibrium-measuring apparatus with the analytical isobaric−isothermal method, and then, the measured data were correlated with the Peng−Robinson equation of state (PR EOS) and Soave−Redlich−Kwong equation of state (SRK EOS), in combination with different mixing rules of Adachi−Sugie, Melhem, and Panagiotopoulos−Reid. Compared with the correlation derivations from different models, the model of PR EOS + PR mixing rule leads to a relatively satisfactory correlation for the 1-methylnaphthalene + CO 2 system.