Existing space application networks in space stations are mainly fiber-optic cable-based networks due to their low size, weight, and power (SWaP) values. While fiber networks in space stations offer data transmission at high speeds with minimal signal loss, their major disadvantage is the lack of flexibility and mobility when new and unplanned space scientific equipment is added to the network. To enhance the flexibility of space networks while increasing their throughput, this paper introduces the hybrid space network (HSN), a new space network architecture that incorporates an optical wireless link, to meet the ever-increasing demands for larger bandwidth and higher mobile access capabilities in space scientific experiments. To best utilize the HSN’s system performance, we propose a multi-priority-based network scheduling scheme, which can dynamically adapt to the requirements of mass tasks and select the best transmission procedure. Through simulations, we find that by adding optical wireless communication (OWC) links to the state-of-the-art deterministic FC-AE-1553 space network, the HSN’s bandwidth can be increased by 20 times with an average latency reduction of 87.3%. We believe that the proposed HSN’s architecture may ultimately shape the future of space stations’ wireless connectivity, and in the meantime, innovate many advanced space applications with larger data rates and mobility requirements.