Lithium
iron phosphate (LFP) pouch batteries are likely to swell
under overcharge conditions, failing the module structure. An overcharge
experiment was carried out on an LFP battery module composed of 72
LFP pouch cells. The experimental results show that the pouch LFP
cell has a large deformation even at a low temperature (below ∼60
°C), and the deformation mainly occurs during the overcharge
voltage plateau period. After overcharge, the average temperature
increase of the module is 46 °C, and the overcharge voltage increases
by 15 V. A novel gas swelling model, which is suitable for both pouch
cells and prismatic cells, is proposed for the first time to realize
the cell swelling caused by increased internal pressure. The interaction
between cells is simulated under different working conditions, including
a swelling cell contact with a normal cell (working condition I) and
two swollen cells interact (working condition II). The simulation
results show that the volume change offset can reach 277.6% under
the internal pressure of 32434 Pa. The contact pressure is greater
when both of the cells swell, causing an easily burst of the cell.
In this paper, the initial contact in working condition II occurs
when the SOC is 110% and the peak contact pressure is 28 N mm–2. The simulation and experimental results can provide
numerical support for understanding the interaction mechanism between
cells during overcharge.