In this paper, W-Mo-Y co infiltration were carried out on the surface of 45 steel wedge components by plasma solid-state surface metallurgy technology. The phase, hardness, friction and wear properties before and after W-Mo co infiltration and W-Mo-Y co infiltration were systematically studied. The diffusion kinetics such as diffusion coefficient and diffusion activation energy were calculated by Fick's second diffusion law, and the effect of Y on the diffusion of W and Mo atoms in the infiltrated layer was obtained. It is found that the addition of rare earth Y element increases the diffusion coefficient of W and Mo atoms and reduces the diffusion activation energy, which has a certain catalytic effect. And the W-Mo-Y co infiltration significantly improves the surface hardness and wears resistance of the parts and prolongs the service life of the parts.