The freezing method compensates for the defect of sacrificing coal integrity to reduce gas content, which is the case with traditional methods, achieving the improvement of coal body strength while reducing coal seam gas energy storage, improving the safety of coal and gas outburst accidents in deep coal seams during the process of rock cross-cut coal uncovering. This study conducted water injection and low-temperature freezing experiments on coal/rock samples under the gas atmosphere, analyzing the effects of water and temperature on sample temperature, deformation, and gas adsorption and desorption characteristics. The results indicate that water can displace adsorbed gas in coal/rock samples, and the relationship between the gas displacement and the water content of the sample satisfies an improved exponential function. The center temperature Tm of low water content coal/rock samples decreases with time and gradually tends to stabilize, while the Tm of high water content samples experiences a short-term deceleration or stagnation due to the phase transition heat release of water when it drops to around 0 °C. The cooling rate of samples with low water content and no gas is higher and that of rocks is higher than that of coal samples. Coal/rock samples with high water content experience frost heave during the freezing process, but the overall deformation is still dominated by cold shrinkage, and the amount of deformation is negatively correlated with temperature and water. The gas adsorption capacity of coal decreases linearly with the temperature. At the same time, an increase in water content and a decrease in freezing temperature will significantly reduce the gas desorption capacity of coal samples, effectively reducing the gas expansion energy of coal samples, especially the desorption gas expansion energy. In engineering implementation of this method, the ice phase network can fill the coal pores and cracks and improve the mechanical properties of the coal/rock mass, and the gas pressure in the coal seam and stress concentration near the coal rock interface can be reduced by low temperature and cold shrinkage, thereby achieving safe exposure of the coal seam and preventing accidents from occurring.