Urban-rural economic opportunity gaps drive rural youth to seek economic stability by migrating away from home and family. The links between educational attainment and economic outcomes for rural youth are well studied in China and elsewhere, but the implications of educational mobility for rural family relationships remain less understood. Extending tenets of second demographic transition theory, we posit that education sets the stage for “individualization:” geographic mobility for urban work distant from rural family networks. Educational mobility may thus set conditions for upending traditional family co-residence patterns, direct-support relationships, and family-gender attitudes. In this paper, we consider first whether educational advancement is associated with urban economic mobility for rural youth in young adulthood, and then ask whether education is linked to disruption of rural family relations. Specifically, using the case of children growing up in rural northwest China, we estimate relationships between secondary and tertiary educational attainment and (1) economic stability, (2) intergenerational geographic separation and material exchange, and (3) traditional family and gender role attitudes, after adjusting for potential confounders. Results show that for both men and women, education is associated with greater economic stability in young adulthood, across several measures, and with an erosion of adherence to traditional family and gender attitudes. Moreover, for men, education correlates to less family proximity and more material exchange.