Research Progress in Metal-Organic Framework Based Nanomaterials Applied in Battery Cathodes

Mechili, Maria; Vaitsis, Christos; Argirusis, Nikolaos; Pandis, Pavlos K.; Sourkouni, Georgia; Zorpas, Antonis A.; Argirusis, Christos

doi:10.3390/en15155460

Cited by 5 publications

(2 citation statements)

References 157 publications

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“…[ 31 ] Therefore, the development of high‐performance aqueous ZIBs using the Mn(BTC) cathodes and the ZIF‐8@Zn anodes exhibited remarkable long‐cycling stability with no discernible capacity degradation after 900 charge/discharge cycles. More recently, Michili et al [ 32 ] also reviewed the importance and recent progress of MOF‐based cathode nanomaterials for various batteries such as metal‐ion and metal–air batteries.…”

Section: Introductionmentioning

confidence: 99%

Metal–Organic Frameworks‐Based Cathode Materials for Energy Storage Applications: A Review

et al. 2023

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Metal-organic framework (MOF) are a kind of highly organized porous crystalline material that has attracted significant interest in several applications, including chemical sensors, organic-, photo-, and electrocatalysis, and energy and environmental applications. [1][2][3][4][5][6] Yaghi et al. are pioneers in the development of MOF-based porous materials using organic linkers and metal-oxide clusters as anchors to create open frameworks. [7] MOFs are readily manufactured by reacting metal ions or clusters with organic linkers in the presence of aqueous or organic solvents at certain temperatures, resulting in crystalline powders or granules. [8] The use of solvent is also playing an effective role in the synthesis of uniform MOFs in addition to other parameters. The solvent used in synthesis remains inside the pores of the collected crystalline framework. These holes may be cleaned out using a more volatile solvent and vacuum-aided desorption, leaving behind an enormous void pore volume. [8] These activated MOFs are calcined further to operate for target-specific analyte adsorption and applications. By varying the chemical compositions of metal and organic linkers, a highly adaptable and adjustable porous architecture may be readily created. [9] MOFs may also provide different internal surfaces with distinct accessible metal sites, various structural topologies, and chemical variety, such as the usage of

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Section: Introductionmentioning

confidence: 99%

Metal–Organic Frameworks‐Based Cathode Materials for Energy Storage Applications: A Review

et al. 2023

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“…Lately, metal-organic framework (MOF) derived materials have gradually developed into promising anode materials for LIBs [20][21][22]. The broad investigation and utilization of MOFs are attributed to the highly-tunable and skeletal structures, and high surface-tovolume ratios, which contribute to the structural stability and electrical conductivity [23][24][25]. Therefore, MOFs with 3D pore architecture are rapidly developed and widely applied in energy storage, gas absorption, electrochemical, etc.…”

Section: Introductionmentioning

confidence: 99%

Microwave-Assisted Metal-Organic Frameworks Derived Synthesis of Zn2GeO4 Nanowire Bundles for Lithium-Ion Batteries

et al. 2023

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Germanium-based multi-metallic-oxide materials have advantages of low activation energy, tunable output voltage, and high theoretical capacity. However, they also exhibit unsatisfactory electronic conductivity, sluggish cation kinetics, and severe volume change, resulting in inferior long-cycle stability and rate performance in lithium-ion batteries (LIBs). To solve these problems, we synthesize metal-organic frameworks derived from rice-like Zn2GeO4 nanowire bundles as the anode of LIBs via a microwave-assisted hydrothermal method, minimizing the particle size and enlarging the cation’s transmission channels, as well as, enhancing the electronic conductivity of the materials. The obtained Zn2GeO4 anode exhibits superior electrochemical performance. A high initial charge capacity of 730 mAhg−1 is obtained and maintained at 661 mAhg−1 after 500 cycles at 100 mA g−1 with a small capacity degradation ratio of ~0.02% for each cycle. Moreover, Zn2GeO4 exhibits a good rate performance, delivering a high capacity of 503 mA h g−1 at 5000 mA g−1. The good electrochemical performance of the rice-like Zn2GeO4 electrode can be attributed to its unique wire-bundle structure, the buffering effect of the bimetallic reaction at different potentials, good electrical conductivity, and fast kinetic rate.

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The Active Role of Conjugate Polymer Composites in Electrochemical Storage: A Themed Perspective on Polymer-MOF Nanocomposites for Metal-Ion Batteries

Vallem

2023

Green Energy and Technology

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Research Progress in Metal-Organic Framework Based Nanomaterials Applied in Battery Cathodes

Cited by 5 publications

References 157 publications

Metal–Organic Frameworks‐Based Cathode Materials for Energy Storage Applications: A Review

Metal–Organic Frameworks‐Based Cathode Materials for Energy Storage Applications: A Review

Microwave-Assisted Metal-Organic Frameworks Derived Synthesis of Zn2GeO4 Nanowire Bundles for Lithium-Ion Batteries

The Active Role of Conjugate Polymer Composites in Electrochemical Storage: A Themed Perspective on Polymer-MOF Nanocomposites for Metal-Ion Batteries

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