2021
DOI: 10.1002/tcr.202000186
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Research Progress in Organic Synthesis by Means of Photoelectrocatalysis

Abstract: The rapid development of radical chemistry has spurred several innovative strategies for organic synthesis. The novel approaches for organic synthesis play a critical role in promoting and regulating the single‐electron redox activity. Among them, photoelectrocatalysis (PEC) has attained considerable attention as the most promising strategy to convert organic compounds into fine chemicals. This review highlights the current progress in organic synthesis through PEC, including various catalytic reactions, catal… Show more

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Cited by 81 publications
(34 citation statements)
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“…The adsorbed N 2 molecules on the surface of Au could be hydrogenated to form N 2 H x species (1 < x < 4) with the rate-determining step of N 2 dissociation . Moreover, Au-based catalysts can also achieve a higher FE for NRR than platinum (Pt)-based catalysts in the previous reports, suggesting that Au possesses more attached active centers of N atoms rather than H atoms. , For example, Li et al. found that the Au-loaded reduced graphene oxide (RGO) or CeO x exhibited 11 times higher NH 3 yield rate than the single RGO or CeO x catalysts .…”
Section: Introductionmentioning
confidence: 99%
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“…The adsorbed N 2 molecules on the surface of Au could be hydrogenated to form N 2 H x species (1 < x < 4) with the rate-determining step of N 2 dissociation . Moreover, Au-based catalysts can also achieve a higher FE for NRR than platinum (Pt)-based catalysts in the previous reports, suggesting that Au possesses more attached active centers of N atoms rather than H atoms. , For example, Li et al. found that the Au-loaded reduced graphene oxide (RGO) or CeO x exhibited 11 times higher NH 3 yield rate than the single RGO or CeO x catalysts .…”
Section: Introductionmentioning
confidence: 99%
“…Electrocatalytic N 2 reduction reaction (NRR) is supposed to be as an alternative technique for N 2 fixation because of its renewable electricity sources and moderate proceeding conditions. Unfortunately, there are still no suitable electrocatalysts that can be used in practical industrial production because of limited N 2 absorption and serious side reactions of hydrogen evolution reaction (HER). Therefore, it is desirable to implement an efficient strategy to improve the chemisorption of N 2 molecules and inhibit competitive reactions of HER, thereby enhancing the activity and selectivity of NRR catalysts. Previous studies have demonstrated several available strategies such as exposing more active sites, tuning the electrolyte, boosting N 2 mass transfer, and reducing water transport. …”
Section: Introductionmentioning
confidence: 99%
“…In particular, there is a need to study in more detail the dependence of mechanical and photoelectrochemical properties, as well as electron transfer mechanisms in order to improve the efficiency, stability, and cost of catalysts. Li et al [ 11 ] pay attention to the peculiarities of the occurrence of PEC reactions in organic synthesis. In particular, the oxidation of benzene and aliphatic alcohols, the activation and amination of C-H and so on are considered.…”
Section: Introductionmentioning
confidence: 99%
“…Therefore, the exploration of a clean, efficient, and sustainable NH 3 production method remains a huge challenge. Several strategies for NH 3 synthesis by artificial nitrogen fixation have been developed, including electrocatalysis, photocatalysis, and biological strategies. The electrocatalytic nitrogen reduction reaction (NRR) for NH 3 production stands out among many NH 3 production methods due to its advantages of having a mild, safe, controllable, and simple process.…”
Section: Introductionmentioning
confidence: 99%