Research Status of Metal–Organic Frameworks for On‐Board Cryo‐Adsorptive Hydrogen Storage Applications

Dailly, Anne

doi:10.1002/9783527635856.ch7

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2023

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“…Several companies commercialize MOFs to adsorb hazardous gases or for the dosing of compounds that prevent fruit ripening. [185][186][187][188][189] They are limited to small-scale applications because large-scale applications such as CO 2 adsorption or natural gas storage are limited by a number of constraints. Perhaps the most important is the low thermal conductivity of MOFs.…”

Section: Summary and Perspectivesmentioning

confidence: 99%

Post‐Synthetic Surface Modification of Metal–Organic Frameworks and Their Potential Applications

Figueroa-Quintero

Villalgordo-Hernández

Delgado-Marín

et al. 2023

Small Methods

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Metal–organic frameworks (MOFs) are porous hybrid materials with countless potential applications. Most of these rely on their porous structure, tunable composition, and the possibility of incorporating and expanding their functions. Although functionalization of the inner surface of MOF crystals has received considerable attention in recent years, methods to functionalize selectively the outer crystal surface of MOFs are developed to a lesser extent, despite their importance. This article summarizes different types of post‐synthetic modifications and possible applications of modified materials such as: catalysis, adsorption, drug delivery, mixed matrix membranes, and stabilization of porous liquids.

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