We have scattered protons and hydrogen atoms with energies of some keV from a LiF(001) surface under a grazing angle of incidence. From the intensity of Lyman-a radiation (transition from n 2 to n 1, l 121.6 nm) as a function of projectile energy for different azimuthal orientations of the crystal surface, we find clear evidence for a resonant coherent excitation of n 2 states of hydrogen atoms in the oscillating electric field in front of the insulator surface. [S0031-9007(97)04713-3] PACS numbers: 79.20. Rf, 34.50.Fa, 34.70. + e When fast atoms or ions interact with a crystal under channeling conditions the target atoms induce oscillating electric fields in the projectile frame. Okorokov [1] predicted that for a corresponding setting of the projectile velocity and the crystal orientation these fields will stimulate a resonant coherent excitation (RCE) of electronic states in the projectiles. Early experiments with He 1 ions after the passage through thin crystal foils were not conclusive [2-4], since loosely bound electrons will not survive within the bulk of a metal. First evidence for RCE in a crystal was reported by Datz and co-workers [5-7] by observation of charge fractions of tightly bound hydrogenlike and heliumlike ions with MeV energies after the passage through thin crystals of Au and Ag. The enhanced ionization probabilities for electronically excited ions lead, under resonance conditions, to modified charge fractions which provide an unequivocal signature of RCE in a solid. Kupfer et al. [8] proposed to make use of the electric fields that extend to the vacuum region in front of a solid and to excite electronic transitions in projectiles scattered in front of the surface ("surface channeling"). Attempts to observe RCE via optical transitions in He 1 ions failed [9]; however, recently Kimura et al.[10] found evidence for RCE by observing changes in the B 41 ͞B 51 charge ratios for MeV boron ions scattered under grazing incidence from a SnTe(100) surface. A structure in those ratios at a projectile energy of about 5.85 MeV is attributed to the n 1 to n 2 excitation of hydrogenlike boron ions ͑B 41 ͒ via the second harmonic of the oscillating electric fields in front of the surface.In this Letter we report on the first observation of RCE obtained for the scattering of fast atomic projectiles from the surface of an ionic crystal, here LiF(001). Our experiments demonstrate that making use of insulator instead of metal surfaces results in new attractive features which make ionic crystals well suited for detailed studies on resonant coherent excitation phenomena induced in the interaction of atomic projectiles with a solid target. We present results on the excitation of n 2 in atomic hydrogen studied by the subsequent decay via Lyman-a radiation ͑l 121.6 nm͒. This work can be considered as the first successful resonant excitation of atomic levels with loosely bound electrons (binding energy some eV) in the interaction of fast atoms with solid matter.Making use of an ionic crystal surface instead of metal ...