We show that a pure spin current can be injected in quantum wells by the absorption of linearly polarized infrared radiation, leading to transitions between subbands. The magnitude and the direction of the spin current depend on the Dresselhaus and Rashba spin-orbit coupling constants and light frequency and, therefore, can be manipulated by changing the light frequency and/or applying an external bias across the quantum well. The injected spin current should be observable either as a voltage generated via the anomalous spin-Hall effect, or by spatially resolved pump-probe optical spectroscopy.Spin current is an interesting physical phenomenon in its own right, and could have application in the delivery and transfer of electron spins in spintronics devices. From a fundamental point of view, various issues raised in the theory of this effect are far from being satisfactorily settled. As was shown by Rashba 1 , a spin current exists even in the equilibrium state of a two-dimensional (2D) electron gas with spin-orbit (SO) coupling. The application of an external electric field has been suggested as a strategy for driving the system out of equilibrium and inducing a spin current exhibiting transport effects. Mal'shukov et al. 2 and Governale et al. 3 suggested applying a time-dependent bias across a semiconducting heterostructure, thus modulating the strength of the SO coupling and generating a spin current. Murakami et al. 4 and Sinova et al. 5 have shown that an in-plane electric field can cause a spin current, leading to the "intrinsic spin-Hall effect". Another possibility for the injection of spin current is coherently controlled optical excitations between the valence and the conduction band, as predicted by Bhat and Sipe 6,7 and observed experimentally in bulk crystals 8,9 and quantum wells (QWs) 10 .Here we show that a spin current can be injected in QWs by infrared (IR) light absorption, driving transitions between different subbands. The injection of spin-polarized electric current in QWs due to intersubband transitions caused by circularly polarized radiation has already been observed by Ganichev et al. 11 . In contrast, here we investigate a pure spin current, where electrons moving in opposite directions have opposite orientations of spins, not accompanied by a net electrical current. We show that the strength and direction of this pure spin current can be manipulated by modulating the SO coupling strength via applied bias 12 and/or adjusting the light frequency.As an example we consider the (011) GaAs QW, where the electron spins have a considerable out-of plane component, thus making possible the observation of the pure spin current by detecting the voltage generated via the anomalous spin-Hall effect 13,14 . The first two subbands in the well are typically separated by the energyhω 0 ≈ 100 meV; the exact value depends on the width of the QW, dopant concentration, and the boundary conditions. The SO Hamiltonian for the (011) QW, H SO = H D + H R , is the sum of a Dresselhaus term 15 , H D , originatin...