Dynamics of metal availability and toxicity in historically polluted floodplain sediments van der Geest, H.G.; Leon Paumen, M.
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IntroductionRestoration of riverine floodplains alongside the regulated large European rivers can play an important role in the management of floods by reduction of peak discharges and increase of water storage capacity. Proposed measures include setting back dikes, lowering or removing groynes and embankments, extracting accumulated sediments from the floodplains and excavation of secondary channels in the floodplain (Buijse et al., 2002). However, these measures might also have negative consequences because many floodplains contain high concentrations of sediment associated contaminants. Overbank sedimentation and disposal of dredged sediments resulted in increased concentrations of heavy metals, PACs and other organic toxicants in floodplain soils and sediments (Middelkoop, 2000;Gocht et al., 2001;Winter et al., 2001) that might induce toxic effects (De Haas et al., 2002). Newly constructed side-channels that are foreseen as means to re-naturalize floodplains will have banks that cut through the aged polluted sediments that have in the meantime been covered by cleaner sediment. The banks of these newly created river channels are characterized by a highly dynamic transition zone (Simons et al., 2001), in which toxicants might be subjected to large changes in terms of mobility, transformation and bioavailability ( Van den Berg et al., 1999). On a large scale, differences may be observed between erosion and sedimentation areas and between areas