“…Moreover, as the separation mechanism of filtration membranes is normally explained in terms of surface charge and/or size exclusion (i.e., a sieving effect), [145] additional studies [131] have been undertaken to understand the selectivity of the sub-2-nm DWCNT membranes toward ion rejection or passage through the nanotube pores as a function of solution concentration, pH, ion valence and ion size. [128,131] At low pH (3.8), the surface carboxyl groups of the acid-treated nanotubes were protonated resulting in a neutral membrane, whereas at higher pH (7.2), the ionized carboxyl groups imparted an overall negative charge to the membrane surface.…”