Filtering
facepiece respirators (FFRs) protect wearers from inhalation
of fine particulates and help prevent transmission of airborne viruses.
Here, an FFR material is produced by successive deposition of contact
drawn poly(ethylene oxide) (PEO) fibers. Fibers are formed by immersing
an array of pins in a highly viscous precursor solution of PEO and
then rapidly removing the pins such that polymer entanglement occurs,
forming multiple liquid bridges that rapidly dry as they extend. Tunable
filtration is achieved by varying the number of PEO fiber elongation
cycles. Placing the PEO textiles between two woven cotton cloths provides
structural support and additional filtration capacity, achieving a
maximum filtration efficiency of 95% with a corresponding initial
pressure drop of 281 Pa. The entrapment of silver nanoparticles in
the PEO fibers imparts virucidal properties to PEO-based textiles,
as demonstrated by inactivation of a human coronavirus HCoV-OC43 and
influenza A virus inoculum. The ability to tune filtration efficiency
to application needs and provide advanced function through entrapment
of active materials represents a versatile tool for limiting exposure
to airborne particulates and pathogens.