2020
DOI: 10.26434/chemrxiv.13022606.v1
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Reversibility in a Plastically Flexible Coordination Polymer Crystal: A High-Pressure Study

Abstract: <p>Single crystals which exhibit mechanical flexibility are promising materials for advanced technological applications. Before such materials can be used, detailed understanding of the mechanisms and structural effects of bending are needed. Coordination polymer single crystal represent a fascinating class of mechanically flexible material; their bending contradicts existing models. Using single crystal X-ray diffraction and microfocus Raman spectroscopy, we study in atomic detail the high-pressure resp… Show more

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Cited by 2 publications
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“…co-grinding dry solid reagents or with negligible amount of solvents) are an attractive alternative to conventional solution-based synthesis. 40 This environmentally benign technique has been extensively applied for rapid and high-yielding synthesis of wide range of molecules and materials including cocrystal, 41,42 organometallic complexes, 43 MOFs, 44,45 and composites. 46 Recently, mechanochemical syntheses have been utilized for preparation of porous MOFs for different functional applications, 44 while proton conductive MOFs are still scarce.…”
Section: Introductionmentioning
confidence: 99%
“…co-grinding dry solid reagents or with negligible amount of solvents) are an attractive alternative to conventional solution-based synthesis. 40 This environmentally benign technique has been extensively applied for rapid and high-yielding synthesis of wide range of molecules and materials including cocrystal, 41,42 organometallic complexes, 43 MOFs, 44,45 and composites. 46 Recently, mechanochemical syntheses have been utilized for preparation of porous MOFs for different functional applications, 44 while proton conductive MOFs are still scarce.…”
Section: Introductionmentioning
confidence: 99%
“…The ability to adapt to external mechanical stimuli with precise and predictable responses is still relatively rare among molecular crystals. Endowing crystalline materials with such features enables a range of advanced practical applications in, e.g., flexible electronics and magnetic or optoelectronic devices. , Crystalline coordination polymers (CPs) are, due to their tunable magnetic and electronic properties, of particular interest in this context, but unfortunately, only a handful of such compounds have been found to display elastic , or plastic flexibility in response to external mechanical pressure.…”
Section: Introductionmentioning
confidence: 99%