2019
DOI: 10.1016/j.ceramint.2019.03.255
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Reversible redox behavior of Fe2O3/TiO2 composites in the gaseous photodegradation process

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Cited by 45 publications
(11 citation statements)
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“…From Figure h, the peaks at 100.9, 103.2, and 104.9 eV were all attributed to Hg 2+ , so the mercury is mainly present on the surface of the sample in the form of mercury oxide. It can be concluded that the De-Cu 30 /TiO 2 sample can photocatalytically oxidize zero-valent mercury to a less toxic product when illuminated . The three O 1s peaks of De-Cu 30 /TiO 2 before and after the reaction are very similar, but the O 1s peak of De-Cu 30 /TiO 2 after the removal of Hg 0 moves 0.2 eV toward the direction of high BE, indicating that charge transfer to the electron acceptor occurs during the reaction (Figure i).…”
Section: Resultsmentioning
confidence: 93%
“…From Figure h, the peaks at 100.9, 103.2, and 104.9 eV were all attributed to Hg 2+ , so the mercury is mainly present on the surface of the sample in the form of mercury oxide. It can be concluded that the De-Cu 30 /TiO 2 sample can photocatalytically oxidize zero-valent mercury to a less toxic product when illuminated . The three O 1s peaks of De-Cu 30 /TiO 2 before and after the reaction are very similar, but the O 1s peak of De-Cu 30 /TiO 2 after the removal of Hg 0 moves 0.2 eV toward the direction of high BE, indicating that charge transfer to the electron acceptor occurs during the reaction (Figure i).…”
Section: Resultsmentioning
confidence: 93%
“…The strength of the chemical bond is stronger than that of van der Waals forces and other physical forces, so the coating of nano-TiO 2 on a SiO 2 surface is stable . The TiO 2 @Si:Fe nanoparticles then lie on the sheets of rGO. , …”
Section: Materials and Methodsmentioning
confidence: 99%
“…19 The TiO 2 @Si:Fe nanoparticles then lie on the sheets of rGO. 20,21 The final sol produced, TiO 2 @Si:Fe:rGO and the intermediate sols TiO 2 , TiO 2 @Si, and TiO 2 @Si:Fe were then applied to metallic substrates, consisting of commercial purity titanium specimens, grade 2 ASTM, with dimensions 50 mm × 50 mm and thickness 0.5 mm. All specimens were coated in the TiO 2 @Si:Fe:rGO sol with the dipcoating method.…”
Section: Methodsmentioning
confidence: 99%
“…These results were in agreement with other work already done with the aim of doping TiO 2 with iron oxides. 5,18 An accurate determination of the band gap energy is also necessary because it is a decisive characteristic in terms of determining the electronic structure of materials especially in the case of doping. It is also important that the type of band-toband transition in these synthesized catalysts should be established.…”
Section: Diffuse Reectance Spectroscopymentioning
confidence: 99%