Reversible thermochromic polydiacetylene/Zn(II) ion assemblies prepared via co-assembling in aqueous phase: The essential role of pH

Pattanatornchai, Thanutpon; Rueangsuwan, Jirapa; Phonchai, Natthanon; Traiphol, Nisanart; Traiphol, Rakchart

doi:10.1016/j.colsurfa.2020.124649

Cited by 24 publications

(18 citation statements)

References 49 publications

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“…The preparation under basic conditions provides reversible thermochromic MNCs with T CT ∼ 90 °C. The effect of the pH on the thermochromic behaviors is parallel with our previous study on the system of PDA/Zn 2+ assemblies …”

Section: Resultssupporting

confidence: 83%

“…The peak at 1693 cm –1 disappears upon increasing the pH to 10, while the peak at 1540 cm –1 becomes dominant. Our previous work showed that the presence of OH – ions promoted coordination between the PDA carboxylate headgroups and Zn 2+ ions during self-assembly . The results in this study indicate that most carboxylate headgroups coordinate with the Zn 2+ ions at pH 10, providing fully reversible thermochromism.…”

Section: Resultssupporting

confidence: 52%

“…The increase of the interlamellar d -spacing value compared to that of pure PDA(8,12) suggests the intercalation of Zn 2+ ions with the bilayer structure, as illustrated in Figure b. We note that the Zn 2+ -intercalated bilayer structure of PDA(8,12)/Zn 2+ assemblies and PDA(8,12)/Zn 2+ /ZnO nanocomposites exhibits the same interlamellar d -spacing value. , Detailed analysis of the XRD results in the PDA/Zn 2+ /ZnO nanocomposite system also indicates increases of the molecular tilting angle with respect to the lamellar plane …”

Section: Resultsmentioning

confidence: 66%

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ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

Kingchok

Nontasorn

Laohhasurayotin

et al. 2021

ACS Appl. Nano Mater.

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Nanocomposites of polydiacetylene (PDA) and magnetic nanoparticles (MNPs), exhibiting irreversible thermochromism, have shown potential for use as nanothermometers. This type of nanocomposite, however, does not allow measurement of the real-time temperature. In this study, we introduce the first example of magnetic PDA-based nanocomposites, exhibiting reversible thermochromism and colorimetric response to both acidic and basic conditions. Zinc ferrite magnetic nanoparticles (ZnFe2O4-MNPs) decorated the surface of PDA/Zn2+ assemblies, forming PDA/Zn2+/ZnFe2O4 magnetic nanocomposites. The intercalation of Zn2+ ions, released from ZnFe2O4-MNPs, with PDA bilayers via strong interaction with a carboxylate headgroup provides reversible thermochromism. This reversible thermochromic nanocomposite with magnetic properties is ideally suited for advanced applications requiring precise local thermal or pH sensing. For instance, the magnetothermally induced thermochromism of PDA could be implemented for real-time measurement of the local temperature (e.g., magnetic hyperthermia), visualization of the magnetic field, and many other related applications. In addition, the colorimetric response of this material to acids and bases makes possible measurement of the local pH in a small-scale environment, localized at a target area, focused using an external magnetic field.

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Section: Resultssupporting

confidence: 83%

Section: Resultssupporting

confidence: 52%

Section: Resultsmentioning

confidence: 66%

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ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

Kingchok

Nontasorn

Laohhasurayotin

et al. 2021

ACS Appl. Nano Mater.

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“…Two bands appeared at 3500–3300 and 1638 cm –1 for MCDA-Ni , which are assignable to H 2 O vibrational frequencies (HOH), whereas these were absent in MCDA-MA (Figure a). In addition, the infrared (IR) spectrum showed a shift in the value of carbonyl ν(CO) stretching frequency of MCDA-MA from 1691 to 1544 cm –1 in MCDA-Ni , which indicates the formation of a metal–ligand coordination complex between the carboxyl group and Ni ion, O–Ni (Figure b). , X-ray photoelectron spectroscopy (XPS) is a powerful technique for the elemental identification of all surface elements. Hence, to get more insight into metal–ligand coordination between MCDA-MA and the Ni ion, XPS analysis was performed.…”

Section: Resultsmentioning

confidence: 99%

Nickel-Ion-Coordinated Reversibly Solvatochromic Polydiacetylene Based on Tubular Assembly of Macrocyclic Diacetylene

2021

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Polydiacetylenes (PDAs) present excellent chromogenic characteristics and have been extensively utilized as a sensory polymeric material to design and fabricate colorimetric sensor systems. Herein, we describe a Ni 2+ -ion-directed reversibly solvatochromic tubular PDA based on macrocyclic diacetylene (MCDA). A dimeric MCDA complex was formed through Ni 2+intercalated coordinative binding with carboxyl groups, which later transform into blue-phase PDA upon UV irradiation. Infrared spectral analysis confirmed the presence of structural water molecules coordinating to central Ni 2+ , which predicted to fulfill the octahedral geometry. Spectroscopic studies for the reversible blue−red chromatic behavior revealed a very unusual and unprecedented chromatic switching mechanism originating due to localized structural disruption at the Ni 2+ coordination site that leads to torsion in the π-conjugated backbone for chromatic changes, in contrast to the typical residual monomeric dissolutioninduced mechanism. This unusual behavior can be attributed to the coordinating water molecules, which presents an attractive advantage by creating a hydrophilic pocket at the coordination site and allows interactions with hydrophilic solvents causing structural distortion.

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“…Materials containing PCDA and PCDA derivatives have been successful in the detection of different metal ions, including alkali metals (lithium, sodium, , and cesium , ), transition metals (chromium(III), manganese(II), nickel(II), copper(II), zinc(II), − silver(I), , cadmium(II), ,, iridium(III), gold(III), and mercury(II), ,, ), post-transition metals and metalloids (aluminum(III), arsenic(III), , tin(IV), and lead(II) ,,− ), and the lanthanide element terbium(III). , Many PCDA systems incorporating metal ions exhibit reversible thermochromism due to the enhanced electrostatic interactions between the cations and the carboxylate headgroup of PCDA, allowing the structural recovery of the conjugated backbone after the heat stimulus is removed . Nanocomposites comprising the intercalation of zinc oxide nanoparticles into PCDA assemblies have been studied by powder X-ray diffraction to investigate the effect of metal ions on the interlamellar d spacing of PCDA .…”

Section: Optical and Electronic Properties Of Polydiacetylenesmentioning

confidence: 99%

Properties and Applications of Stimuli-Responsive Diacetylenes

Hall

Musa

Steed

2021

Crystal Growth & Design

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The topochemical reactivity of diacetylene monomers has long been established and involves the 1,4-addition polymerization reaction. This reaction is governed by well-defined parameters that allow the synthesis of diacetylene polymers. Polydiacetylenes are conjugated polymers that display unique colorimetric and fluorescent transitions when they are exposed to a range of stimuli, allowing them to be easily exploited in biosensors, chemosensors, and radiochromic dosimeters. In this review, we summarize recent work on polydiacetylene systems, focusing on examples involving 10,12-pentacosadiynoic acid (PCDA) that can be structured as polymerized vesicles, films, gels, and powders. Synthetic derivatives of PCDA are also reviewed, along with the effect of incorporating guest molecules to a diacetylene system and establishing the important relationship between reversible thermochromism and noncovalent interactions.

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Reversible thermochromic polydiacetylene/Zn(II) ion assemblies prepared via co-assembling in aqueous phase: The essential role of pH

Cited by 24 publications

References 49 publications

ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

Nickel-Ion-Coordinated Reversibly Solvatochromic Polydiacetylene Based on Tubular Assembly of Macrocyclic Diacetylene

Properties and Applications of Stimuli-Responsive Diacetylenes

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Reversible thermochromic polydiacetylene/Zn(II) ion assemblies prepared via co-assembling in aqueous phase: The essential role of pH

Cited by 24 publications

References 49 publications

ZnFe2O4 Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

ZnFe2O4 Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

Nickel-Ion-Coordinated Reversibly Solvatochromic Polydiacetylene Based on Tubular Assembly of Macrocyclic Diacetylene

Properties and Applications of Stimuli-Responsive Diacetylenes

Contact Info

Product

Resources

About

ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors

ZnFe₂O₄ Magnetic Nanoparticle–Polydiacetylene–Zinc(II) Composites for Real-Time Nanothermometers and Localizable Acid/Base Sensors