2022
DOI: 10.1039/d2cp03945a
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Reversibly switchable methanofullerene by photoexcitation and reduction

Abstract: Cyclopropanated derivative of the trifluoromethylated fullerene Cs-C70(CF3)8 demonstrates reversible switching behavior triggered by excited state electron transfer or by negative charging. The switching between the state with connected 62-electron π-system...

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Cited by 4 publications
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“…Recently, we have surveyed the optical properties of the cyclopropanated C s -C 70 (CF 3 ) 8 [C(PhOMe) 2 ] where the 4C(PhOMe) 2 moiety is attached to the same near-equatorial [5,6]-bond. 36 The compound reveals interesting switching behavior due to opening/ closure of the said bond triggered by either photoexcitation or reduction to the anionic state. A further study of cycloaddition to C s -C 70 (CF 3 ) 8 carried out in the presence of pyridine and oxygen has, unexpectedly, produced cage-opened products instead of the cycloadducts.…”
mentioning
confidence: 99%
“…Recently, we have surveyed the optical properties of the cyclopropanated C s -C 70 (CF 3 ) 8 [C(PhOMe) 2 ] where the 4C(PhOMe) 2 moiety is attached to the same near-equatorial [5,6]-bond. 36 The compound reveals interesting switching behavior due to opening/ closure of the said bond triggered by either photoexcitation or reduction to the anionic state. A further study of cycloaddition to C s -C 70 (CF 3 ) 8 carried out in the presence of pyridine and oxygen has, unexpectedly, produced cage-opened products instead of the cycloadducts.…”
mentioning
confidence: 99%