2023
DOI: 10.26434/chemrxiv-2023-ds47k
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Revisiting peri-aryloxyquinones: From a forgotten photochromic system to a promising tool for emerging applications

Andrey Lvov,
Lyubov Klimenko,
Vasily Bykov
et al.

Abstract: Emerging applications of photochromic compounds demand new molecular designs that can be inspired by some long-known yet currently forgotten classes of photoswitches. In the present review, we would like to remind the community about Peri-AryloxyQuinones (PAQs) and their unique photoswitching behavior originally discovered by Gerasimenko more than 50 years ago. At the heart of this phenomenon is the light-induced migration of an aromatic moiety (arylotropy) in peri-aryloxy-substituted quinones resulting in ana… Show more

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