2019
DOI: 10.26434/chemrxiv.8937017.v2
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Rh(III)-Catalyzed Coupling of N-Chloroimines with α-Diazo-α-Phosphonoacetates for Skeleton-Oriented Synthesis of 2H-Isoindoles

et al.

Abstract: A major hurdle for realizing the full potential of transition metalcatalyzed, directed C-H functionalization synthesis of heterocycles is the blockingof ability for designated structural elaboration by the reactivity-assisting groupderived, unintended appendages. We communicate herein Rh(III)-catalyzed coupling of N-chloroimines with α-diazo-α-phosphonoacetates for skeletonoriented synthesis (SOS) of 2H-Isoindoles. Comprehensive mechanistic studies with rhodacycle intermediates support an associative covalent … Show more

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