Rheological and thermal study of structured oils: avocado (Persea americana) and sacha inchi (Plukenetia volubilis L.) systems

Herazo, Merly Álvarez; Velásquez, Héctor José Ciro; Márquez, Carlos J.

doi:10.1007/s13197-018-3492-4

Cited by 4 publications

(2 citation statements)

References 30 publications

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“…This was likely due to the dynamic forces generated in the shearing process causing the fracture of the crystalline structure of stigmasterol organogels [ 40 ]. Similar results have been reported in many organogel structures with pseudoplastic properties [ 40 , 41 , 42 ]. The relationship between the apparent viscosity and shear rate of organogels prepared with different concentrations of stigmasterol is consistent with the power-law equation.…”

Section: Resultssupporting

confidence: 90%

Structure and Properties of Organogels Prepared from Rapeseed Oil with Stigmasterol

Tang

Wan

Chen

et al. 2022

Foods

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This work used the natural ingredient stigmasterol as an oleogelator to explore the effect of concentration on the properties of organogels. Organogels based on rapeseed oil were investigated using various techniques (oil binding capacity, rheology, polarized light microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy) to better understand their physical and microscopic properties. Results showed that stigmasterol was an efficient and thermoreversible oleogelator, capable of structuring rapeseed oil at a stigmasterol concentration as low as 2% with a gelation temperature of 5 °C. The oil binding capacity values of organogels increased to 99.74% as the concentration of stigmasterol was increased to 6%. The rheological properties revealed that organogels prepared with stigmasterol were a pseudoplastic fluid with non-covalent physical crosslinking, and the G’ of the organogels did not change with the frequency of scanning increased, showing the characteristics of strong gel. The microscopic properties and Fourier transform infrared spectroscopy showed that stigmasterol formed rod-like crystals through the self-assembly of intermolecular hydrogen bonds, fixing rapeseed oil in its three-dimensional structure to form organogels. Therefore, stigmasterol can be considered as a good organogelator. It is expected to be widely used in food, medicine, and other biological-related fields.

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Section: Resultssupporting

confidence: 90%

Structure and Properties of Organogels Prepared from Rapeseed Oil with Stigmasterol

Tang

Wan

Chen

et al. 2022

Foods

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show abstract

“…41 As indicated above, such HIPPEs show a great potential in foodstuff, particularly in oil-rich compositions. On the basis of the rheological tests, the prepared NCh-stabilized HIPPEs present similar properties (appearance and texture) as margarine 55,56 and mayonnaise, 57 thereby indicating the possibility for HIPPEs as a substitute for related formulations. Stabilization Mechanism.…”

Section: ■ Results and Discussionmentioning

confidence: 89%

High Internal Phase Oil-in-Water Pickering Emulsions Stabilized by Chitin Nanofibrils: 3D Structuring and Solid Foam 

Zhu

Huan

Bai

et al. 2020

ACS Appl. Mater. Interfaces

145

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Chitin nanofibrils (NCh, ∼10 nm lateral size) were produced under conditions that were less severe compared to those for other biomass-derived nanomaterials and used to formulate high internal phase Pickering emulsions (HIPPEs). Pre-emulsification followed by continuous oil feeding facilitated a “scaffold” with high elasticity, which arrested droplet mobility and coarsening, achieving edible oil-in-water emulsions with internal phase volume fraction as high as 88%. The high stabilization ability of rodlike NCh originated from the restricted coarsening, droplet breakage and coalescence upon emulsion formation. This was the result of (a) irreversible adsorption at the interface (wettability measurements by the captive bubble method) and (b) structuring in highly interconnected fibrillar networks in the continuous phase (rheology, cryo-SEM, and fluorescent microscopies). Because the surface energy of NCh can be tailored by pH (protonation of surface amino groups), emulsion formation was found to be pH-dependent. Emulsions produced at pH from 3 to 5 were most stable (at least for 3 weeks). Although at a higher pH NCh was dispersible and the three-phase contact angle indicated better interfacial wettability to the oil phase, the lower interdroplet repulsion caused coarsening at high oil loading. We further show the existence of a trade-off between NCh axial aspect and minimum NCh concentration to stabilize 88% oil-in-water HIPPEs: only 0.038 wt % (based on emulsion mass) NCh of high axial aspect was required compared to 0.064 wt % for the shorter one. The as-produced HIPPEs were easily textured by taking advantage of their elastic behavior and resilience to compositional changes. Hence, chitin-based HIPPEs were demonstrated as emulgel inks suitable for 3D printing (millimeter definition) via direct ink writing, e.g., for edible functional foods and ultralight solid foams displaying highly interconnected pores and for potential cell culturing applications.

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Oleogels: Versatile Novel Semi-Solid System for Pharmaceuticals

Pawar,

Dessai,

Nayak

2024

AAPS PharmSciTech

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Oleogels is a novel semi-solid system, focusing on its composition, formulation, characterization, and diverse pharmaceutical applications. Due to their stability, smoothness, and controlled release qualities, oleogels are frequently utilized in food, cosmetics, and medicinal products. Oleogels are meticulously formulated by combining oleogelators like waxes, fatty acids, ethyl cellulose, and phytosterols with edible oils, leading to a nuanced understanding of their impact on rheological characteristics. They can be characterized by methods like visual inspection, texture analysis, rheological measurements, gelation tests, and microscopy. The applications of oleogels are explored in diverse fields such as nutraceuticals, cosmetics, food, lubricants, and pharmaceutics. Oleogels have applications in topical, transdermal, and ocular drug delivery, showcasing their potential for revolutionizing drug administration. This review aims to enhance the understanding of oleogels, contributing to the evolving landscape of pharmaceutical formulations. Oleogels emerge as a versatile and promising solution, offering substantial potential for innovation in drug delivery and formulation practices. Graphical Abstract

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Rheological and thermal study of structured oils: avocado (Persea americana) and sacha inchi (Plukenetia volubilis L.) systems

Cited by 4 publications

References 30 publications

Structure and Properties of Organogels Prepared from Rapeseed Oil with Stigmasterol

Structure and Properties of Organogels Prepared from Rapeseed Oil with Stigmasterol

High Internal Phase Oil-in-Water Pickering Emulsions Stabilized by Chitin Nanofibrils: 3D Structuring and Solid Foam

Oleogels: Versatile Novel Semi-Solid System for Pharmaceuticals

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