“…In soils over 10 000 years old, changes in soil properties due to soil-forming processes are assumed to be minimal. Changes in soil properties related to tree stand ageing and growth can be explained on the basis of slower mineralization of organic matter due to cooler, moister soil (Bhatti et al 2000), and perhaps to the occurrence of deeper, longer-lasting soil frost caused by the shading of the tree canopies (Yli-Vakkuri 1960, Päivänen 1973, on the basis of nutrient accumulation in tree biomass, the exudation of acidic material (H + and organic compounds) by tree roots (Gobran et al 1998), the accumulation of acidic coniferous litter on and in the soil (Nihlgård 1971), and more acidic soil water percolating down through the forest floor (Alriksson and Olsson 1995, Brais et al 1995, Krause 1998, Griffiths and Swanson 2001. The organic layer becomes thicker, the organic and uppermost mineral soil layers become more acidic, and the nitrogen and base cation concentrations decrease (Tamminen 1991, Brais et al 1995.…”