Due to the negative impact on the environmental using fossil fuels, photovoltaic (PV) technology has become a new alternative for renewable energy in the last two decades. Although inorganic solar cells have dominated in the PV field, metal-free organic compounds have introduced a new challenge because of their great properties that include: i) high light-harvesting ranges, ii) optical-and electrochemical properties can be easily tuned by decorating their structure through a several synthetic approaches, and iii) their technology has high flexibility and low manufacturing cost. In this short review, we depicted our work in the synthesis of organic compounds and their applications in the PV field, specifically in bulk heterojunction solar cells (BHJSCs), dyesensitized solar cells (DSSCs) and organic-inorganic perovskites solar cells (O-IPSCs).