2017
DOI: 10.1039/c6qo00760k
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Rhodanine-based dyes absorbing in the entire visible spectrum

Abstract: A series of new broad-absorbing dyes based on rhodanine derivatives conjugated with triarylamines through a fluorene backbone were synthesized. Spectroscopic and electrochemical characterizations, along with theoretical calculations, revealed interesting properties of the dyes that efficiently absorb in the entire visible spectrum Q4 .Please check this proof carefully. Our staff will not read it in detail after you have returned it.Translation errors between word-processor files and typesetting systems can occ… Show more

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Cited by 6 publications
(4 citation statements)
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“…Splitting of O 1s peak confirms the presence of C–O (533.5 eV) and CO (532 eV) bonds, respectively (Figure C). Chemical driving force (−Δ G PET ∼ 0.95 eV) of PET reaction was calculated from the oxidation and reduction potentials of DMA and GQD and the band gap energy of GQD obtained from Tauc plot or intersection wavelength of normalized absorption and emission spectra. , Details of Δ G PET calculation can be found in the Supporting Information.…”
Section: Results and Discussionmentioning
confidence: 99%
“…Splitting of O 1s peak confirms the presence of C–O (533.5 eV) and CO (532 eV) bonds, respectively (Figure C). Chemical driving force (−Δ G PET ∼ 0.95 eV) of PET reaction was calculated from the oxidation and reduction potentials of DMA and GQD and the band gap energy of GQD obtained from Tauc plot or intersection wavelength of normalized absorption and emission spectra. , Details of Δ G PET calculation can be found in the Supporting Information.…”
Section: Results and Discussionmentioning
confidence: 99%
“…1), referred to colloquially as dicyanorhodanine (RCN), was introduced as an electron acceptor unit for organic optoelectronic materials in 2011. 1 Since then, the RCN acceptor has become a xture within the organic photovoltaic (OPV) community as it can lead to broadened and red-shied absorption extending into the near infrared, 2,3 enhanced crystallinity, 4 and high electron affinities 5 when appended to a p-conjugated molecule. Indeed, there have been 100+ publications relying on the dicyanorhodanine acceptor since 2013, speaking to the important role that this structure has played in the development of OPV materials.…”
Section: Introductionmentioning
confidence: 99%
“…Different organic materials have showed great properties for DSSC applications, and taking a look at their structures, generally they are based on a donor moiety linked covalently to an acceptor moiety [32][33][34]. Several synthetic strategies have been studied to improve the optoelectronic properties of organic dyes, which can be summarized in: i) the use of bulky co-donor systems to block the approach of the electrolyte redox couple to the semiconductor surface avoiding the electronic recombinant processes [35]; ii) the development of novel anchoring units with better optical-and electrochemical properties as well as higher stability in comparison with the conventional carboxylic-based acceptor [36,37] and iii) the improvement of the light harvesting in the red region of the visible spectrum through the π-conjugation increase [38].…”
Section: Dye-sensitized Solar Cellsmentioning
confidence: 99%