Rhodium-Catalyzed [7 + 1] Cycloaddition of Exocyclic 1,3-Dienylcyclopropanes and Carbon Monoxide

Huang, Zhiqiang; Wang, Xin; Jin, Yi; Wang, Zuwei; Yu, Zhi-Xiang

doi:10.1021/acs.orglett.3c03471

Org. Lett.

2023

DOI: 10.1021/acs.orglett.3c03471

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Rhodium-Catalyzed [7 + 1] Cycloaddition of Exocyclic 1,3-Dienylcyclopropanes and Carbon Monoxide

Zhiqiang Huang,

Xin Wang,

Yi Jin

et al.

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2024

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Cited by 3 publications

References 33 publications

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Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4-Cycloheptadienes

Li,

Shen,

et al. 2024

Org. Lett.

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Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4-Cycloheptadienes

Li,

Shen,

et al. 2024

Org. Lett.

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Cyclization reactions of cyclopropane derivatives with conjugated carbo- and heterosystems

Sergeev,

Novikov,

Tomilov

2024

RUSS CHEM REV

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Напряженная структура циклопропанов служит своеобразным "спусковым крючком" для проведения самых разнообразных химических превращений. Особый интерес представляют процессы, протекающие с участием сопряженных непредельных соединений. Системы кратных связей характеризуются возможностью гибкого варьирования реакционной способности, вплоть до их полного вовлечения в трансформацию. В данном обзоре впервые рассмотрены варианты реализации идеи сочетания в рамках единой концепции энергии напряжения циклопропанов и синтетического потенциала сопряженных непредельных соединений. Представлен детальный анализ процессов с участием активированных циклопропанов и различных ненасыщенных карбо- и гетеросистем. <br> Библиография — 289 ссылок.

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Progress in Transition-Metal-Catalyzed Carbonylative Cycloadditions Using Carbon Monoxide

Li,

2024

Chinese Journal of Organic Chemistry

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Transition-metal-catalyzed cycloadditions have been evolved as important and efficient methods to construct cyclic molecules. Among them, transition-metal-catalyzed cycloadditions using carbon monoxide (CO) gas as the 1C synthon provide their unique and powerful approaches to build various cyclic molecules within a carbonyl group, which either acts as an important functional group within the cycloadducts, or can be further elaborated to other functional groups. The tremendous advances in this field are introduced.

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Rhodium-Catalyzed [7 + 1] Cycloaddition of Exocyclic 1,3-Dienylcyclopropanes and Carbon Monoxide

Cited by 3 publications

References 33 publications

Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4-Cycloheptadienes

Rh-Catalyzed trans-Divinylcyclopropane Rearrangement: An Approach to 1,5-Disubstituted 1,4-Cycloheptadienes

Cyclization reactions of cyclopropane derivatives with conjugated carbo- and heterosystems

Progress in Transition-Metal-Catalyzed Carbonylative Cycloadditions Using Carbon Monoxide

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