“… 5 As such, PGEs have been recognized as critical materials . 6 Rhodium (Rh), the focus of this work, is used extensively in heterogeneous and homogeneous catalysis, 7–9 including catalytic converters to decrease emissions from automobiles. Rhodium currently stands as the world's most expensive metal, and existing demands for it exceed what can be fulfilled through recycling and new mining sources.…”
This study demonstrates the application of 103Rh solid-state NMR (SSNMR) spectroscopy to inorganic and organometallic coordination compounds, in combination with relativistic density functional theory (DFT) calculations of 103Rh chemical shift...
“… 5 As such, PGEs have been recognized as critical materials . 6 Rhodium (Rh), the focus of this work, is used extensively in heterogeneous and homogeneous catalysis, 7–9 including catalytic converters to decrease emissions from automobiles. Rhodium currently stands as the world's most expensive metal, and existing demands for it exceed what can be fulfilled through recycling and new mining sources.…”
This study demonstrates the application of 103Rh solid-state NMR (SSNMR) spectroscopy to inorganic and organometallic coordination compounds, in combination with relativistic density functional theory (DFT) calculations of 103Rh chemical shift...
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