Rhodium(<scp>ii</scp>)-catalyzed synthesis of 2-aminoquinoline derivatives from 2-quinolones and <i>N</i>-sulfonyl-1,2,3-triazoles

Kahar, Nilesh M.; Jadhav, Pankaj P.; Dawande, Sudam G.

doi:10.1039/d3ob00971h

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2024

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Cited by 2 publications

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Rhodium(II)‐Catalyzed Denitrogenative Transformations of N‐Sulfonyl‐1,2,3‐Triazoles

Doraghi,

Hossein Morshedsolouk,

Ghofrani

et al. 2024

Eur J Org Chem

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N‐Sulfonyl‐1,2,3‐triazoles are valuable precursors for the generation of α‐imino carbene intermediates in the presence of the metal catalysts, especially rhodium(II) complexes. Due to the presence of electrophilic carbene and nucleophilic nitrogen, these reactive intermediates can easily be incorporated into many annulations, cycloadditions, C‐H or O/N/S‐H bond insertions and functionalization reactions. A large number of pharmaceutically important nitrogen‐based building blocks can be constructed via this direct and atom‐economical carbene strategy. In this review, we have described the transformations of N‐sulfonyl‐1,2,3‐triazoles based on α‐imino rhodium(II) carbene intermediates.

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Rhodium(II)‐Catalyzed Denitrogenative Transformations of N‐Sulfonyl‐1,2,3‐Triazoles

Doraghi,

Hossein Morshedsolouk,

Ghofrani

et al. 2024

Eur J Org Chem

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show abstract

Five-membered ring systems: With more than 1 N atom

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2024

Progress in Heterocyclic Chemistry

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Rhodium(ii)-catalyzed synthesis of 2-aminoquinoline derivatives from 2-quinolones and N-sulfonyl-1,2,3-triazoles

Abstract: An efficient and facile rhodium(ii) catalyzed denitrogenative method for the synthesis of 2-aminoquinoline derivatives from 2-quinolones and N-sulfonyl-1,2,3-triazoles has been described.

Cited by 2 publications

References 60 publications

Rhodium(II)‐Catalyzed Denitrogenative Transformations of N‐Sulfonyl‐1,2,3‐Triazoles

Rhodium(II)‐Catalyzed Denitrogenative Transformations of N‐Sulfonyl‐1,2,3‐Triazoles

Five-membered ring systems: With more than 1 N atom

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