2021
DOI: 10.1002/marc.202170027
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Ring‐Opening Metathesis Polymerization of endo‐ and exo‐Norbornene Lactones

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Cited by 4 publications
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“…Monomer 1 shows a slightly lower rate of polymerization than NB at later stages of polymerization, presumably due to steric hindrance from active poly 1 terminals. Since the chelation of the carbonyl oxygen of endo -NBL to the Ru propagating terminals reduces the ROMP rate, 31 such an interaction is not observed in the ROMP of 1 and 2 . The ring-opening metathesis copolymerization (ROMCP) of 1 and 2 with NB was also kinetically analyzed under similar conditions.…”
Section: Resultsmentioning
confidence: 99%
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“…Monomer 1 shows a slightly lower rate of polymerization than NB at later stages of polymerization, presumably due to steric hindrance from active poly 1 terminals. Since the chelation of the carbonyl oxygen of endo -NBL to the Ru propagating terminals reduces the ROMP rate, 31 such an interaction is not observed in the ROMP of 1 and 2 . The ring-opening metathesis copolymerization (ROMCP) of 1 and 2 with NB was also kinetically analyzed under similar conditions.…”
Section: Resultsmentioning
confidence: 99%
“…endo -Tricyclo[4.2.2.0 2,5 ]deca-3,9-diene-7,8-dicarboxylic anhydride, 11,12 2 , 10 endo -NBLs, and exo -NBLs 31–33 were synthesized according to previously reported procedures.…”
Section: Methodsmentioning
confidence: 99%
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