Ring‐shaped [(TiCl₂)(1,3‐P₂S₈)]₂ Molecules Containing Uncommon [P₂S₈]^2– Anions 

Abstract

Abstract. Intensely red, moisture-sensitive crystals of [(TiCl 2 )(1,3-P 2 S 8 )] 2 were obtained by the reaction of TiCl 4 and P 4 S 10 at room temperature. The crystal structure determination revealed molecules formally consisting of two units of the anion [1,3-P 2 S 8 ] 2-connected with

Synthesis and Characterization of the New Ternary Titanium Thiophosphate TiP2S7 and Comparison to Ti4P8S29

“…Within the surrounding of the Ti atom a disorder is found including a replacement of one S atom by a S 2 dumbbell with a minor occupation of the atomic sites of 5 %, shown in Figure . This disorder resembles to the similar S/S 2 occupational disorder in Ti 4 P 8 S 29 leading to a P 2 S 7 2– ion, and to the more unusual (P 2 S 8 ) 2– , (P 2 S 8 ) 4– , and (P 2 S 9 ) 4– ions including S 2 or even S 3 units connecting two tetrahedra, respectively. The present structure differs as the S 2 dumbbell does not connect two polyhedra but the minor structure model contains a TiS 5 (S 2 ) polyhedron with a slightly unsymmetrical coordination of the S 2 dumbbell.…”

Die rationale Synthese und strukturelle Charakterisierung schwefelreicher Phosphorpolysulfide – α‐P2S7 und β‐P2S7

“…So konnten wir kürzlich die Eisen(III)-katalysierte Bildung von g-P 4 S 6 in CS 2 als Lçsungsmittel beobachten, [16] während bei der Umsetzung von P 4 S 10 mit TiCl 4 in Lçsung [(TiCl 2 )(1,3-P 2 S 8 )] 2 entsteht. [12] Abbildung 3. REM-Aufnahme einer polykristallinen Probe der Phosphorpolysulfide, die deren faserfçrmige Morphologie zeigt.…”

CuTiPS5 – A New Structure Type with a Corrugated Layered Network Structure

“…2-, [2] (P 2 S 8 ) 2-, [6] (P 2 S 8 ) 4-, [5] and (P 2 S 9 ) 4-, [4] which comprise S 2 and S 3 units connecting two tetrahedra, or even (P 2 S 6 ) 4- [1] with a P-P bond. For a strictly alternating sequence a Ti/P ratio of 2/3 is required, which is indeed realized in the structures of ATi 2 P 3 S 12 (A = Li, Na, Ag).…”

“…As a special case of a quaternary compound, TiCl 2 P 2 S 8 contains isolated cyclic [(TiCl 2 ) 2 (P 2 S 8 ) 2 ] units, which are saturated by Cl atoms as part of TiS 4 Cl 2 octahedra. [6] The dimensionality of a respective structure often influences the physical properties, e.g. the structure of the mentioned compounds ATi 2 P 3 S 12 (A = Li, Na, Ag) shows a rigid Ti 2 P 3 S 12 framework with large channels and disordered A cations, and thus these compounds could be appropriate candidates for interesting applications including ion conduction, and the compounds ATi 2 (PS 4 ) 3 with A = Li, Na, Ag have been considered as possible candidates for Li insertion.…”