The aim of this paper is to give a characterization of path connected topological fields, inspired by the classical Gelfand correspondence between a compact Hausdorff topological space X and the space of maximal ideals of the ring of real valued continuous functions C(X, R). More explicitly, our motivation is the following question: What is the essential property of the topological field F = R that makes such a correspondence valid for all compact Hausdorff spaces? It turns out that such a perfect correspondence exists if and only if F is a path connected topological field.