Abstract-This paper concentrates on the problem of control of a hybrid energy storage system (HESS) for an improved and optimized operation of load-frequency control (LFC) applications. The HESS consists of a supercapacitor served as the main power source, and a fuel cell served as the auxiliary power source. Firstly, a Hammerstein-type neural network (HNN) is proposed to identify the HESS system, which formulates the Hammerstein model with a nonlinear static gain in cascade with a linear dynamic block. It provides the model information for the controller to achieve the adaptive performance. Secondly, a feedforward neural network based on back-propagation training algorithm is designed to formulate the PID-type neural network (PIDNN), which is used for the adaptive control of HESS system. Meanwhile, a dynamic anti-windup signal is designed to solve the operational constraint of the HESS system. Then, an appropriate power reference signal for HESS can be generated. Thirdly, the stability and the convergence of the whole system are proved based on the Lyapunov stability theory. Finally, simulation experiments are followed through on a four-area interconnected power system to demonstrate the effectiveness of the proposed control scheme.Index Terms-Load-frequency control (LFC), hybrid energy storage system (HESS), Hammerstein network identification, PIDtype neural network (PIDNN), dynamic anti-windup, adaptive control