different materials that would be electrically charged after being separated. But TE and CE have significant differences. CE occurs just by physical contact of the two materials without rubbing one against the other, but TE is usually inseparably involving friction by rubbing two materials one on the other. Therefore, TE is a "convolution" of two processes between tribology and CE, so that they are inseparable in conventional understanding. We have recently pointed out that CE is a physical effect in science, while TE is an engineering practice that may involve friction and debris. [3] As for the case of solid-solid, CE is defined as a quantum mechanical electron transfer process that occurs for any materials, in any states (solid, liquid, gas), in any application environment, and in a wide range of temperature up to ≈400 °C. Such an effect is universal and is fundamentally unique in nature.
Mechanisms of CEAlthough TE has been known for 2600 years, there is a debate regarding whether CE is due to electron transfer, ion transfer, or even materials species transfer. This is possibly due to the limitation of measurement techniques and the complication of CE by friction process. CE occurs for all phases, including solid, liquid, and gas, and it is the most fundamental phenomenon at an interface. CE occurs between solid-solid, solid-liquid, liquid-liquid, gas-liquid, gas-gas, and gas-solid (Figure 2), and is playing a fundamental role in physics, chemistry, and biology.
Solid-Solid CasesRecently, we found that CE between two solids is dominated, if not exclusively, by electron transfer. [4] CE between metal and dielectric can be well described using the Fermi level model for metal and the surface states model for a dielectric. CE between dielectric and dielectric can be understood using the surface states model. It was found experimentally that CE occurs only when the two materials reach a distance shorter than bonding length, for example, in the repulsive force region in the interaction potential of two atoms (Figure 3b1). As for a general case, an overlapped electron cloud model was first proposed for explaining the electron transition, in which a strong overlap of the electron cloud between two atoms under stress results in a lowered potential barrier between the two, subsequently allowing electron transition from one atom to the other toThe study presents the fundamental scientific understanding of electron transfer in contact electrification in solid-solid and liquid-solid cases and a newly revised model for the formation of electric double layer. The potential revolutionary impacts of triboelectric nanogenerators as energy sources and sensors are presented in the fields of health care, environmental science, wearable electronics, internet of things, human-machine interfacing, robotics, and artificial intelligence.