a b s t r a c tMore and more nanoparticles may be found in the aquatic environment. Effects of different nanoparticles (nano-Al 2 O 3 and nano-TiO 2 ) on the coagulation process in kaolin suspension (with or without humic acid) were investigated. The results indicated that when the pH was 7.0 in kaolin suspension, the strength factor with the presence of TiO 2 increased from 28.79% to 48.69% and when the concentration of TiO 2 was larger than 1.6 mg/L, the strength factor decreased to 23.39%. The removal efficiencies for Al 2 O 3 were 58.27%, 62.73% and 47.3% under pH 6.0, 7.0 or 8.5. The removal efficiencies for TiO 2 were 38.12%, 52.25% and 27.19%. When the concentration of DOC was 2.5 mg/L under pH 7.0, the recovery factor increased from 54.55% to 62.65% with increasing concentration of Al 2 O 3 from 0.0 mg/L to 2.0 mg/L, and it increased from 54.55% to 67.74% for TiO 2 . PACl produced larger flocs, and this may be caused by higher charge neutralization ability and the electrostatic patch effect. The removal efficiency for TiO 2 decreased from 52.25% to 22.13% with increasing concentration of DOC from 0 mg/L to 7.5 mg/L. The removal efficiency for Al 2 O 3 decreased from 62.73% to 32.12%.