This work studied the effect of potassium chloride (KCl)
on soot
formation during the combustion of municipal solid waste (MSW). The
nanostructural and oxidative properties of soot particles were characterized
by high-resolution transmission electron microscopy (HRTEM), X-ray
diffraction (XRD) spectroscopy, Raman spectroscopy (RS), and thermogravimetric
analysis (TGA). HRTEM images showed that, under the same combustion
environment, the KCl-loaded fuel samples generated soot particles
with smaller particle sizes and more compact morphologies. Quantification
of the nanostructure further indicated that, with increasing potassium
concentrations from 1 to 5%, the fringe separation distance and fringe
tortuosity of soot particles slightly increased, yet no clear trend
was observed in the fringe length. Raman spectral analysis verified
the fringe analysis, suggesting that the addition of KCl made the
soot nanostructure more disordered with a larger separation distance
and higher fringe tortuosity. In addition, oxidation profiles determined
that the reactivity of K-doped soot was enhanced because of a decrease
in the apparent activation energy (E
a)
from 167 to 124 kJ/mol. Moreover, E
a showed
strong linearity with the fringe tortuosity and fringe separation
distance, with R
2 values of 0.91 and 0.97,
respectively. On the basis of the experimental data, a schematic of
four K–soot interaction routes is proposed to better understand
the soot formation during the combustion of solid wastes.