Role of aniline in destructing the 1-propanol + toluene azeotrope

Palaniappan, L.; Jaafar, Mohamad Suhaimi

doi:10.1080/10241220902977612

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2016

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“…Exhaustive background about primary alcohols is largely available and their uses in various fields are very evident and need not be emphasized. In particular, for the industrial rectification column, alcohols are frequently used as entrainer/solvent to avoid the formation of azeotropes 3 .…”

Section: Introductionmentioning

confidence: 99%

Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols

Priya¹,

Palaniappan²

2016

Acta Physico-Chimica Sinica

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Sound velocity, density, and viscosity values have been measured at T = 303 K for four binary systems of morpholine + methanol, ethanol, 1-propanol, and 1-butanol. From these data, acoustical parameters, such as adiabatic compressibility, free length, free volume, and internal pressure, have been estimated using the standard relations. The results are interpreted in terms of the molecular interaction between the components of the mixtures. The observed excess values in all the mixtures indicate that the molecular symmetry existing in the system is highly disturbed by the addition of morpholine molecules. The interaction energy terms of the statistical mixing are also verified for these binary systems, and the dipole-dipole interactions are found to be predominant and are greatly affected by the chain length of the primary alkanols.

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Section: Introductionmentioning

confidence: 99%