Role of citric acid in enhancing aromatic hydrogenation performance in Ni-HPW/SiO2 catalysts

Li, Xiaofei; Geng, Lili; Shi, Haifeng; Ye, Songshou; Sim, Ley Boon; Zheng, Jinbao; Zhang, Nuowei; Chen, Binghui

doi:10.1016/j.apcata.2024.119564

Applied Catalysis A: General

2024

DOI: 10.1016/j.apcata.2024.119564

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Role of citric acid in enhancing aromatic hydrogenation performance in Ni-HPW/SiO2 catalysts

Xiaofei Li,

Lili Geng,

Haifeng Shi

et al.

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2024

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Cited by 2 publications

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Enhanced sintering resistance of NiFe‐based RWGS catalysts through Cu doping

Wu,

Zhang,

Chen

et al. 2024

Greenhouse Gases

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The reverse water‐gas shift (RWGS) reaction offers an effective method for mitigating CO2 emissions. Due to its affordability and physicochemical stability, iron has garnered significant attention as a potential catalyst for RWGS. The incorporation of nickel and copper promoters can enhance CO2 conversion and CO selectivity in Fe‐based catalysts. This study focuses on modifying the strength of the Strong Metal‐Support Interaction (SMSI) through particle size optimization. Doping Cu into NiFe‐based catalysts restricts particle size, which influences the curvature of the Ni0@FeOx interface. This curvature enhances the electron coupling between Ni0 and FeOx, promoting the formation of a denser and thicker Ni0 and FeOx layer. This results in a nearly 90% increase in the CO2 reaction rate during the sintering resistance test by anchoring Ni0 and facilitating electron transfer to active sites. Such morphological evolution improves high‐temperature resistance to sintering during RWGS. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.

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Enhanced sintering resistance of NiFe‐based RWGS catalysts through Cu doping

Wu,

Zhang,

Chen

et al. 2024

Greenhouse Gases

View full text Add to dashboard Cite

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Citric acid modulated strong magnetic CoFe-LDH/CoFe2O4 coupled dielectric barrier discharge plasma for efficient levofloxacin degradation: Enhanced internal electric field and accelerated electron migration

Lou,

Han,

Zhang

et al. 2024

Journal of Hazardous Materials

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Role of citric acid in enhancing aromatic hydrogenation performance in Ni-HPW/SiO2 catalysts

Cited by 2 publications

References 41 publications

Enhanced sintering resistance of NiFe‐based RWGS catalysts through Cu doping

Enhanced sintering resistance of NiFe‐based RWGS catalysts through Cu doping

Citric acid modulated strong magnetic CoFe-LDH/CoFe2O4 coupled dielectric barrier discharge plasma for efficient levofloxacin degradation: Enhanced internal electric field and accelerated electron migration

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