According to definition and general agreement, smart materials have properties that can be altered in a controlled fashion by stimuli including stress, temperature, moisture, pH, and electric or magnetic fields. Various recent materials in materials science are in working order, meaning they must achieve their tasks and should go through intentional modification. Smart materials change one or more of their characteristics in response to inputs. They can be called as responsive materials. As these materials have been available for so long, they are used for a wide range of purposes. These qualities have useful applications in many different industries, including dentistry. Zirconia, shape-memory alloys, and SmartSeal obturation system (Prosmart-DRFP Ltd., Stamford, United Kingdom) are a few examples of dental materials with intelligent behavior. The creation of novel materials is a major trend in materials science. These materials might make it possible to develop cutting-edge dental therapies with vastly improved clinical results. This article reviews the following: nickel-titanium smart alloy, smart composites, self-healing composites, smart ceramics, glass ionomer cement as a smart material, SmartSeal obturation system, and smart coatings for dental implants. We can better understand these biosmart materials with the aid of this review. The development of these newer and superior smart materials makes the outcome of the treatment far better for both the operator and the patient.