Role of oxygen vacancy in spinel (FeCoNiCrMn)3O4 high entropy oxides prepared via two different methods for the selective C H bond oxidation of p-chlorotoluene
“…Liang et al prepared Co/CoSe nanocrystalline heterojunction hollow carbon nanospheres, which improved the electron cloud distribution of the material. 163 These composites exhibited high capacity, delivering 461.9 mA h g −1 after 200 cycles at 1 A g −1 and 145.9 mA h g −1 after 3000 cycles at an ultra-high current density of 10 A g −1 . Table 4 consolidates the electrochemical performance of ZIF-derived TMSes as anode materials in recent research.…”
Section: Zif-derived Tmses In Pibsmentioning
confidence: 96%
“…Table 4 consolidates the electrochemical performance of ZIF-derived TMSes as anode materials in recent research. [159][160][161][162][163][164][165][166][167][168] 4.4. ZIF-derived TMPs in PIBs Furthermore, several research groups have demonstrated that TMPs are highly effective in PIBs due to their substantial theoretical capacities and lower polarization potentials.…”
Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) are increasingly recognized as the forefront contenders for the next generation of advanced secondary batteries. The quest for suitable anode materials to enhance...
“…Liang et al prepared Co/CoSe nanocrystalline heterojunction hollow carbon nanospheres, which improved the electron cloud distribution of the material. 163 These composites exhibited high capacity, delivering 461.9 mA h g −1 after 200 cycles at 1 A g −1 and 145.9 mA h g −1 after 3000 cycles at an ultra-high current density of 10 A g −1 . Table 4 consolidates the electrochemical performance of ZIF-derived TMSes as anode materials in recent research.…”
Section: Zif-derived Tmses In Pibsmentioning
confidence: 96%
“…Table 4 consolidates the electrochemical performance of ZIF-derived TMSes as anode materials in recent research. [159][160][161][162][163][164][165][166][167][168] 4.4. ZIF-derived TMPs in PIBs Furthermore, several research groups have demonstrated that TMPs are highly effective in PIBs due to their substantial theoretical capacities and lower polarization potentials.…”
Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) are increasingly recognized as the forefront contenders for the next generation of advanced secondary batteries. The quest for suitable anode materials to enhance...
“…Various modification strategies involving microstructure regulation, heterostructure design and confinement space construction, etc., have been applied to accommodate the volume effect of carbon anodes during the potassium storage process. [112][113][114] Recently, it was shown that the heteroatom-doped carbon materials with expanded interlayer distance can accommodate foreign ion storage and alleviate the volume expansion effect. Wen et al 115 fabricated S/N co-doped carbon nanosheets (S-N-PCNs) as the PIB anode, and non-doped and single-doped samples (PCNs and N-PCNs) were also prepared for comparisons.…”
The development of advanced anode materials to overcome the slow kinetic processes and sever volume expansion of potassium ion batteries (PIBs) is critical for their further application in large-scale energy...
“…The SnO 2 /Sn Schottky heterojunctions were originally constructed to ensure close contact and electronic coupling between SnO 2 and Sn crystal surfaces, which facilitates the reduction of ion adsorption energy at the heterointerfaces. 25 To determine the successful preparation of the Schottky-type SnO 2 /Sn nanorods heterostructures during the experiments, TEM was used to characterize the morphology and structure of SnO 2 /Sn/G samples. As shown in Fig.…”
Herein, to better construct homogeneous heterostructures, we synthesize Schottky heterojunction composites in situ, which utilize a three-dimensional porous graphene carbon material to form more SnO2/Sn/G heterointerfaces and oxygen vacancies.
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