Role of the segment distribution in the microphase separation of acrylic diblock and triblock terpolymers

Bergman, James A.; Cochran, Eric W.; Heinen, Jennifer M.

doi:10.1016/j.polymer.2014.05.049

Cited by 14 publications

(12 citation statements)

References 59 publications

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“…Due to EP and PU have disparate mechanical properties at room temperature; quantitative nanomechanical property mapping is quite suitable for detection of phase distribution in the gradient IPN [17,46,47]. Fracture surface of the gradient composite was prepared as the same in the contact angle measurement.…”

Section: Afm Analysismentioning

confidence: 99%

Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

Zhang

Shi

et al. 2017

Applied Sciences

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A thickness gradient interpenetrating polymer network (IPN) was easily created that takes advantage of the relatively poor compatibility and curing rates discrepancy between epoxy (EP) and polyurethane (PU). Ultraviolet absorption spectrum (UV-Vis), thermogravimetric (TG), Differential scanning calorimetry (DSC), Dynamic thermomechanical analysis (DMA), Atomic force microscope (AFM) and water contact angle were adopted to characterize this IPN structure. We found that the absorption in visible light region, glass-transition temperatures (T g ), thermal decomposition temperatures (T d ) and Derjaguin-Muller-Toporov (DMT) modulus were increasing along with the gradient direction from bottom side to top side of the IPN. While the absorption in ultraviolet region and adhesion force were decreasing along with the gradient direction from bottom side to top side of the IPN. DMA analysis demonstrates that this continuous gradient IPN has a good balance between the damping temperature range and the loss factor which is suitable for using as a self-supporting damping structure.

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Section: Afm Analysismentioning

confidence: 99%

Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

Zhang

Shi

et al. 2017

Applied Sciences

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“…Hyperbranched poly(AESO)s (PAESOs) were synthesized via different conditions spanning a range of monomer and initiator concentrations. ETMP as the CTA was selected in this study due to its good control of acrylic monomers, studied extensively by J. Bergman et al [18,19]. The proper rate of addition-fragmentation of ETMP ensures equal probability of all chain growth, minimizing the chances of network formation by uncontrolled free radical polymerization [1].…”

Section: Resultsmentioning

confidence: 99%

“…1,4dioxane (reagent grade, Fisher Scientific), and hydroquinone (quinol crystalline powder, 99%, Fisher Scientific) were used as received. Ethyl 2-(ethoxycarbonothioylthio)-2-methylpropanoate (ETMP) as chain transfer agent was synthesized following the method reported by Bergman [18].…”

Section: Methodsmentioning

confidence: 99%

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Structure architecture and property relation of hyperbranched polymer produced from triglyceride via RAFT polymerization

Yan¹

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“…Bergman et al have recently observed that slopes far below 1/3 but not equal to zero for a gyroid kind of structure could be because of slippage around grain boundaries, they had very strong indication from SAXS measurement pointing towards Q 230 microstructure. 149 It can be observed that the terminal response is horizontal indicating a solid like behavior.…”

Section: Rheology Analysismentioning

confidence: 97%

Polyolefin/layered silicate nanocomposites via surface initiated ring opening metathesis polymerization

Kalluru¹

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Role of the segment distribution in the microphase separation of acrylic diblock and triblock terpolymers

Cited by 14 publications

References 59 publications

Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

Structure architecture and property relation of hyperbranched polymer produced from triglyceride via RAFT polymerization

Polyolefin/layered silicate nanocomposites via surface initiated ring opening metathesis polymerization

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