2016
DOI: 10.1007/s11144-016-0991-z
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Role of the sulfonamide moiety of Ru(II) half-sandwich complexes in the asymmetric transfer hydrogenation of 3,4-dihydroisoquinolines

Abstract: The role of the sulfonamide moiety of Noyori-Ikariya [Ru(II)Cl(g 6 -pcymene)(S,S)-(N-arylsulfonyl-DPEN)] (where DPEN = 1,2-diphenylethylene-1,2-diamine) half-sandwich complexes in the asymmetric transfer hydrogenation (ATH) of imines (1-methyl-3,4-dihydroisoquinoline and 6,7-dimethoxy-1-methyl-3,4-dihydroisoquinoline) was investigated. Nine complexes were synthesized and characterized, most of which have not been previously reported and a majority of the corresponding ligands (N-arylsulfonyl-DPEN) have not bee… Show more

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Cited by 6 publications
(1 citation statement)
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“…The role of sulfoonamide moiety of Noyori-based catalysts [Ru(II)Cl(η 6 p cymene)(S,S)-(Narylsulfonyl-DPEN) in the asymmetric transfer hydrogenation of two cyclic imine substrates (1-methyl-3,4-dihydroisoquinoline and 6,7 dimethoxy-1-methyl-3,4-dihydroisoquinoline) was also investigated [24]. All together, nine complexes, differing in substitution of the aromatic ring of the ligand, were synthesized and characterized, most of which have not been previously reported and the majority of the corresponding ligands have not been described in imine ATH.…”
Section: Comparison Of the Different Sulfonyl Moieties In The Ath Of mentioning
confidence: 99%
“…The role of sulfoonamide moiety of Noyori-based catalysts [Ru(II)Cl(η 6 p cymene)(S,S)-(Narylsulfonyl-DPEN) in the asymmetric transfer hydrogenation of two cyclic imine substrates (1-methyl-3,4-dihydroisoquinoline and 6,7 dimethoxy-1-methyl-3,4-dihydroisoquinoline) was also investigated [24]. All together, nine complexes, differing in substitution of the aromatic ring of the ligand, were synthesized and characterized, most of which have not been previously reported and the majority of the corresponding ligands have not been described in imine ATH.…”
Section: Comparison Of the Different Sulfonyl Moieties In The Ath Of mentioning
confidence: 99%