We study the Li isotopes systematically in terms of the tensor-optimized shell model (TOSM) by using a bare nucleon-nucleon interaction as the AV8 ′ interaction. The short-range correlation is treated in the unitary correlation operator method (UCOM). Using the TOSM+UCOM approach, we investigate the role of the tensor force on each spectrum of the Li isotopes. It is found that the tensor force produces quite a characteristic effect on various states in each spectrum and those spectra are affected considerably by the tensor force. The energy difference between the spin-orbit partner, the p 1/2 and p 3/2 orbits of the last neutron, in 5 Li is caused by opposite roles of the tensor correlation. In 6 Li, the spin-triplet state in the LS coupling configuration is favored energetically by the tensor force in comparison with jj coupling shell model states. In 7,8,9 Li, the low-lying states containing extra neutrons in the p 3/2 orbit are favored energetically due to the large tensor contribution to allow the excitation from the 0s-orbit to the p 1/2 orbit by the tensor force. Those three nuclei show the jj coupling character in their ground states which is different from 6 Li.