2015
DOI: 10.1002/adma.201502560
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Roll‐to‐Roll Green Transfer of CVD Graphene onto Plastic for a Transparent and Flexible Triboelectric Nanogenerator

Abstract: A novel roll-to-roll, etching-free, clean transfer of CVD-grown graphene from copper to plastic using surface-energy-assisted delamination in hot deionized water is reported. The delamination process is realized by water penetration between the hydrophobic graphene and a hydrophilic native oxide layer on a copper foil.The transferred graphene on plastic is used as a high-output flexible and transparent triboelectric nanogenerator.

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Cited by 291 publications
(240 citation statements)
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“…PTFE, PET, PI, PDMS, PMMA) and inorganic materials (e.g. ITO, Al, Cu, Au, Ti, TiO 2 , Si) have been utilized for fabricating TENG and showed outstanding performance 16, 19, 56. Recently, various of advanced materials also have been studied, including graphene,57 carbon nanotube,58 paper,59 nano‐Ag ink,60 degradable polymers etc61 ( Figure 7 ).…”
Section: Materials and Device Designmentioning
confidence: 99%
“…PTFE, PET, PI, PDMS, PMMA) and inorganic materials (e.g. ITO, Al, Cu, Au, Ti, TiO 2 , Si) have been utilized for fabricating TENG and showed outstanding performance 16, 19, 56. Recently, various of advanced materials also have been studied, including graphene,57 carbon nanotube,58 paper,59 nano‐Ag ink,60 degradable polymers etc61 ( Figure 7 ).…”
Section: Materials and Device Designmentioning
confidence: 99%
“…Note that the absorption of substrate is taken off. Moreover, the sheet resistance of graphene/EVA is measured as 3124 Ω sq −1 , which is much lower than the value (≈5200 Ω sq −1 ) in the previous report 23. In addition, Figure 5e demonstrates the electrical conductivity of graphene transferred onto EVA plastic.…”
mentioning
confidence: 57%
“…First, the adhesion energy (1.5 eV)20 of Ga on graphene must be basically matched with the adhesion energy of graphene–TS, which offers a possibility for the tight contact to realize the successful transfer of graphene. Generally, the commonly employed target substrates, such as SiO 2 /Si,21 quartz,22 and flexible and transparent materials (EVA)23 all can be good choices because of the matched adhesion energies. However, only the matched adsorption will not make a successful transfer.…”
mentioning
confidence: 99%
“…This is why the FOM of copercolating hybrids behave as if they are classical thin films, except with much higher performance. Although the nanotrough involved more difficult processing, the network itself has very little tube-tube resistance, and therefore, offers significantly improved performance [30]. Moreover, the use of earth-abundant materials addresses an important criticism of TCO-based technologies.…”
Section: Copercolating Hybrid Tces Obviates the Percolation Bottlenecksmentioning
confidence: 99%
“…Recently, a number of applications of hybrid AgNW-graphene have been demonstrated in the literature ranging from its use as electrodes in light-emitting diodes to atomically thin barrier layer for protection against high-energy radiation [21,29,30,[52][53][54][55][56][57][58][59][60][61]. The schematic shown in Figure 6 summarizes the recent progress in the field and Table 2 presents their key physical properties.…”
Section: Multifunctional Applications Of Copercolating Hybrid Tcesmentioning
confidence: 99%