Roll‐to‐Roll Manufacturing of Breathable Superhydrophobic Membranes

Abstract

Self‐cleaning and anti‐biofouling are both advantages for lotus‐leaf‐like superhydrophobic surfaces. Methods for creating superhydrophobicity, including chemical bonding low surface energy molecular fragments and constructing surface morphology with protrusions, micropores, and trapped micro airbags by traditional physical strategies, unfortunately, have encountered challenges. They often involve complex synthesis processes, stubborn chemical accumulation, brutal degradation, or infeasible calculation and imprecise modulation in fabricating hierarchical surface roughness. Here, a scalable method to prepare high‐quality, breathable superhydrophobic membranes is proposed by developing a successive roll‐to‐roll laser manufacturing technique, which offers advantages over conventional fabrication approaches in enabling automatically large‐scale production and ensuring cost‐effectiveness. Nanosecond laser writing and femtosecond laser drilling produce surface microstructures and micropore arrays, respectively, endowing the membrane with superior antiwater capability with hierarchical microstructures forming a barrier and blocking water infiltration. The membrane's breathability is carefully optimized by tailoring micropore arrays to allow for the adequate passage of water vapor while maintaining superhydrophobicity. These membranes combine the benefits of anti‐aqueous corrosive liquid behaviors, photothermal effects, thermoplastic properties, and stretchable performances as promising comprehensive materials in diverse scenes.