Room Temperature Synthesis and Characterization of a Zn (II) based Metal- organic Framework with Mixed Ligands, 1, 4- Benzenedicarboxylic Acid and 1-methyle Imidazole

Zinc metal–organic framework with 3-pyridinecarboxaldehyde and trimesic acid as co-ligands for selective detection of Cr (VI) ions in aqueous solution

“…The weight loss in about 15% within the range of 160 °C-390 °C could be as a result of the release of free water and DMF molecules from the pores of the particles. The second weight loss from about 390 °C was as a result of the decomposition of the MOF due to the removal of phenyl rings as well as carboxylate groups that were present [34]. The Zn(3ALPy)(TMA) decomposed further and after 510 °C, the 42 wt% corresponds approximately to the metallic Zn particles.…”

Ionic liquid@MIL-101 prepared via the ship-in-bottle technique: remarkable adsorbents for the removal of benzothiophene from liquid fuel

“…Fig. 2 shows the FT-IR spectra of IL@MIL-101s, where the strong band at 1105 cm À1 and medium bands at 1288 and 1232 cm À1 were attributed to the C-N stretching and imidazole ring stretching vibrations respectively, [33][34][35] confirming the presence of ILs in the obtained material. Elemental analyses of the adsorbents were also performed to detect any IL element present after washing of IL@MIL-101.…”

Emerging Trends in Coordination Polymers and Metal-Organic Frameworks: Perspectives, Synthesis, Properties and Applications

“…Many methods abounds for the synthesis of nanoparticles of coordination polymers or nanoparticles of metal organic frameworks but all of the processes takes advantage of reduced solubility of the particles in comparison of the individual components. Common methods rountinely used include solvothermal synthesis, simple mixing of precursor solutions, precipitation by rapid addition of a poor solvent, high-temperature surfactant-assisted synthesis and reverse microemulsion synthesis [1,2,26]. Specifically, a nanoparticle metal organic framework with the formula Zr 6 O 6 (OH) 4 (BDC) (BDC = 1,4-benzenedicarboxylate) was made by the solvothermal method.…”