Room temperature synthesis of 1,5-benzodiazepine and its derivatives using cage type mesoporous aluminosilicate catalysts

Synthesis of 1,5-Benzodiazepine and Its Derivatives by Condensation Reaction Using H-MCM-22 as Catalyst

“… Reaction mechanism of the synthesis of 1,5-benzodiazepines using H-MCM-22 catalyst at room temperature [ 29 ]. …”

Porous Catalytic Systems in the Synthesis of Bioactive Heterocycles and Related Compounds

“…Vinu et al were the first to report the synthesis of 1,5-benzodiazepine through a condensation reaction between o-phenylenediamine and ketones in acetonitrile, at room temperature, over AlKIT-5 catalysts [165]. Aluminum-supported mesoporous KIT-5 materials (AlKIT-5) proved to be highly active catalysts due to their high acidity, high surface area, large pore volume, and cage-type 3D porous structure.…”

Synthesis of KIT‐5 decorated by Bi2S3‐Fe3O4 photocatalyst for degradation of parathion pesticide in aqueous media: Offering a degradation model and optimization using response surface methodology (RSM)

“…KIT‐5 was believed to be preferred to 1D mesoporous silica's, because the interconnected 3D large pores were profitable for mass transport of reactants and products, and producing more available adsorption sites . Hence, KIT‐5 is favorable catalyst support for different reactions …”

“…[26] Hence, KIT-5 is favorable catalyst support for different reactions. [27][28][29] Functionalization of photocatalysts by combining magnetic nanoparticles allows their effective recovery using an external magnetic field. Current researches described that magnetite nanoparticle (Fe 3 O 4 ) is an excellent heterogeneous catalyst than other iron oxides, [30,31] probably owing to the Fe 2+ in its structure can help to increase OH generation.…”