Room‐Temperature Synthesis of Air‐Stable and Size‐Tunable Luminescent ZnS‐Coated Cd<sub>3</sub>P<sub>2</sub> Nanocrystals with High Quantum Yields

Ojo, Wilfried-Solo; Xu, Shu; Delpech, Fabien; Nayral, Céline; Chaudret, Bruno

doi:10.1002/anie.201104864

Cited by 33 publications

(46 citation statements)

References 16 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These effects are due to the decrease of fluxionality resulting from the coordination and/or interaction with the NPs, as previously noted when a surfactant molecule interacted with a nanoparticle surface. 10,25,26 They also strongly support the coordination through the carboxylate moiety and the proximity of its olefin function to the surface of the NPs.…”

Section: Surface-ligand Composition and Dynamicsmentioning

confidence: 67%

See 1 more Smart Citation

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles

et al. 2015

View full text Add to dashboard Cite

The synthesis of germanium nanoparticles has been carried out, thanks to the design of novel aminoiminate germanium(II) precursors: (ATI)GeZ (with Z = OMe, NPh2, and ATI = N,N'-diisopropyl-aminotroponiminate) and (Am)2Ge (Am = N,N'-bis(trimethylsilyl)phenyl amidinate). These complexes were fully characterized by spectroscopic techniques as well as single crystal X-ray diffraction. The thermolysis of both complexes yielded NPs which display similar features that are a Ge/GeO2 core/shell structure with a mean diameter close to 5 nm with a narrow size distribution (<15%). Whereas the high temperatures (>300 °C) classically reported in the literature for the preparation of germanium-based NPs were necessary for thermolysis of the complexes (ATI)GeZ, the use of amidinate-based precursors allows the preparation at an unprecedented low temperature (160 °C) for the thermolytic route. As suggested by a mechanistic study, the lower reactivity of (ATI)GeZ (for which the concomitant use of high temperature and acidic reagent is required) was explained in terms of lower ring strain compared to the case of (Am)2Ge.

show abstract

Section: Surface-ligand Composition and Dynamicsmentioning

confidence: 67%

“…CCDC 983765 and 983766. For ESI and crystallographic data in CIF or other electronic format see DOI: 10 An ideal case would be a low-temperature synthesis with no salt by-product, i.e. involving halide-free germanium species incorporating labile substituents.…”

Section: Introductionmentioning

confidence: 99%

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles

et al. 2015

View full text Add to dashboard Cite

show abstract

“…These QDs can be synthesized at RT and thus, side-reactions which are known to occur at high (300 °C) or moderately high (150 °C) temperature are avoided. 8,20 In addition, the surface chemistry of these QDs is versatile and can be modified in order to introduce various ligands and to test the limits of this method.…”

mentioning

confidence: 99%

“…of HDA. 20 After 2 h and the subsequent work-up, spheroidal Cd 3 P 2 QDs of 2.4(0.3) nm are obtained. The UV-Vis, PL spectra, XRD data and TEM picture are provided in Fig.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Identifying short surface ligands on metal phosphide quantum dots

Baquero

Ojo

Coppel

et al. 2016

Phys. Chem. Chem. Phys.

Self Cite

View full text Add to dashboard Cite

show abstract

25th Anniversary Article: Exploring Nanoscaled Matter from Speciation to Phase Diagrams: Metal Phosphide Nanoparticles as a Case of Study

et al. 2013

View full text Add to dashboard Cite

The notions of nanoscale "phase speciation" and "phase diagram" are defined and discussed in terms of kinetic and thermodynamic controls, based on the case of metal phosphide nanoparticles. After an overview of the most successful synthetic routes for these exotic nanomaterials, the cases of InP, Ni2 P, Ni12 P5 and Pdx Py are discussed in detail to highlight the relationship between composition, structure, and size at the nanoscale. The influence of morphology is discussed next by comparing the behavior of Cu3 P nanophases with those of Nix Py , FeP/Fe2 P, and CoP/Co2 P. Perspectives provide the reader with methodological guidelines for further investigation of nanoscale "phase diagrams", and their use for optimized synthesis of new functional nanomaterials.

show abstract

Room‐Temperature Synthesis of Air‐Stable and Size‐Tunable Luminescent ZnS‐Coated Cd₃P₂ Nanocrystals with High Quantum Yields

Cited by 33 publications

References 16 publications

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles

Identifying short surface ligands on metal phosphide quantum dots

25th Anniversary Article: Exploring Nanoscaled Matter from Speciation to Phase Diagrams: Metal Phosphide Nanoparticles as a Case of Study

Contact Info

Product

Resources

About

Room‐Temperature Synthesis of Air‐Stable and Size‐Tunable Luminescent ZnS‐Coated Cd3P2 Nanocrystals with High Quantum Yields

Cited by 33 publications

References 16 publications

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO2nanoparticles

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO2nanoparticles

Identifying short surface ligands on metal phosphide quantum dots

25th Anniversary Article: Exploring Nanoscaled Matter from Speciation to Phase Diagrams: Metal Phosphide Nanoparticles as a Case of Study

Contact Info

Product

Resources

About

Room‐Temperature Synthesis of Air‐Stable and Size‐Tunable Luminescent ZnS‐Coated Cd₃P₂ Nanocrystals with High Quantum Yields

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles

From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO₂nanoparticles