1977
DOI: 10.1002/jrs.1250060506
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Rotation‐vibrational bands of gaseous allene‐d4

Abstract: Many of the fundamental bands of aUene-d4 have been analysed to yield a number of molecular constants, including the ground state constants A. -Bo = 2.1832 f 0.0004 cm-' and Dm, = (2.8 f 0.2) x cm-'. A reassignment of the perpendicular bands u, and ull is proposed.

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Cited by 13 publications
(3 citation statements)
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“…From previous analysis [2][3][4] ground state constants and upper state constants for the v o and vl0 levels are available. The ground state constants are collected in table 1.…”
Section: Observed Spectra and Assignmentsmentioning
confidence: 99%
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“…From previous analysis [2][3][4] ground state constants and upper state constants for the v o and vl0 levels are available. The ground state constants are collected in table 1.…”
Section: Observed Spectra and Assignmentsmentioning
confidence: 99%
“…Our final fit was to the following set of 14 constants : the vibrational band origin, A rotational constant and the Coriolis coupling parameter (A~) for all three individual bands; D K and the vibrational l resonance constant for the 2vlo and the 2v 9 bands ; the Coriolis interaction parameter W9,10 defined in (2). The remaining constants could not be determined with significance and they were therefore constrained to their predicted values as given in table 2, column I.…”
Section: Q Branch Analysismentioning
confidence: 99%
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