Reduced transition probabilities between the low-lying states of 132 Ba were measured using the Coulomb excitation technique. The experiment was performed at Inter University Accelerator Center (IUAC), New Delhi using a 58 Ni beam of 175 MeV energy to Coulomb excite the 132 Ba nuclei. In addition to the 2 + 1 state, other states in 132 Ba, such as 2 + 2 and 4 + 1 , were populated, the latter for the first time using Coulomb excitation. A set of matrix elements was extracted for the transitions between these levels. These values were determined relative to 134 Ba excitations to minimize the systematic errors. A B(E2; 0 + gs → 2 + 1 ) value of 1.088(85) e 2 b 2 was determined, corresponding to ∼ 54.5 single-particle units.